Production components of motor fuels by processing blends of straight-run diesel fraction and sunflower oil on a zeolite catalyst

D. V. Sosnina, A. Altynov, I. Bogdanov, M. Kirgina
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Abstract

The development of processes for the co-processing of vegetable oils and petroleum hydrocarbons, the purpose of which is to production components of motor-fuels, is an important direction in the development of the fuel and energy industry. An important stage in the planning and implementation of such processes is the selection of a catalyst. Recently, zeolites of various structures and modifications have become very popular as catalysts. In this work, processing on a zeolite catalyst of the ZSM-5 type of a straight-run diesel fraction and a blend of a diesel fraction with 50% vol. sunflower oil, were implementation. Regularities of the effect of sunflower oil involvement in processing on a zeolite catalyst on the composition and properties of the obtained products are revealed. It has been established that the products of joint processing of sunflower oil and straight-run diesel fraction on a zeolite catalyst meet to the arctic brand of diesel fuel in terms of low-temperature properties. It is shown that the obtained product of processing on zeolite is a promising blending component for the production of low-freezing diesel fuels. The received results indicate the feasibility of joint processing of vegetable oils and straight-run diesel fractions on zeolite catalysts. The involvement of vegetable oils in processing will expand the pool of feedstock for the production of motor-fuel components.
通过在沸石催化剂上处理直馏柴油馏分和葵花籽油的混合物,生产发动机燃料的组分
开发植物油和石油烃的协同加工工艺,以生产发动机燃料的组成部分,是燃料和能源工业发展的一个重要方向。规划和实施这类过程的一个重要阶段是催化剂的选择。近年来,各种结构和改性的沸石作为催化剂得到了广泛的应用。在这项工作中,在ZSM-5型直馏柴油馏分和柴油馏分与50%体积葵花籽油的混合物的沸石催化剂上进行了处理。揭示了葵花籽油在沸石催化剂加工过程中对产物组成和性能的影响规律。在沸石催化剂上联合处理葵花籽油和直馏柴油馏分的产物,其低温性能符合柴油的北极品牌。结果表明,沸石加工所得的产物是生产低凝点柴油的一种很有前途的掺合组分。实验结果表明,在沸石催化剂上联合处理植物油和直馏柴油馏分是可行的。植物油参与加工将扩大生产发动机燃料部件的原料池。
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