Rhodium(II) carboxylates

T. Ho, M. Fieser, L. Fieser, R. Danheiser, W. Roush, Janice Y. Smith
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引用次数: 5

Abstract

This article has no abstract. Keywords: cyclopropanation with alkyl diazoacetates; cyclopropenation; thiophenium ylides; cyclopropanation; β-lactams; β-keto esters from α-diazo-β-hydroxy esters; buchner reaction; cyclopropanation of ; 2-carbapenems; alkylation of β-lactams; intramolecular cycloaddition of a diazo ketone to a cyclopropene; cyclopentanones; cis-α,β-unsaturated esters; unsaturated ethers; δ-lactones; chiral cyclopentanones; intramolecular buchner reaction; hydroformylation; benzyl ketones; cyclization-cycloaddition of an α-diazoacetophenone; chiral 3,3-disubstituted cyclopentanones; intramolecular C—H insertion; oxepanes and oxocanes; cyclopropanation of furanyl diazo ketones; β-lactams; α-silyl esters or ketones; diazo ketone cyclization to hydroazulenones; cyclization/cycloaddition route to oxapolycycles; 2,5-disubstituted 3(2H)-furanones; furans; carbenoid–monothiophthalimide coupling; rearrangement of N-nitrosoamides; tropones; reaction of α-diazo ketones with alkynes; synthesis of (+)-griseofulvin (3); reaction of cyclic diazo-1,3-dicarbonyls with aryl heterocycles; tricyclic dihydropyrrolizines; reaction with cyclopropenes; α-alkoxy esters; insertion into SiH bonds; heterocyclization; silylformylation; carbenoid insertions; cyclopropanation; heterocycles; conjugated ketenes; hydroformylation; carbenoid insertions; rearrangements; four-membered rings; diheterobicycloalkanes; [3 + 2]cycloadditions; wolff rearrangement; three-membered rings; five-membered rings; C-H insertion; rearrangement; 1-acetoxyazulenes; coupling; transylidation; bond insertion; bicyclization; benzyl alcohols; N-sulfonylcarboxamides; isomerization; arylation; CH Bond Insertion; NH Bond Insertion; NO Bond Insertion; cyclization; rhenium(VII) oxide; Rh/alumina catalyst hydrogenation; rhodium - iron; rhodium(I) hexafluoroantimonate; ruthenium(III) chloride hydrate
铑(II)羧化物
这篇文章没有摘要。关键词:烷基重氮乙酸酯环丙烷化;cyclopropenation;thiophenium内鎓盐;摘要总结;β-lactams;α-重氮-β-羟基酯生成的β-酮酯;毕希纳反应;环丙烷化;2-carbapenems;β-内酰胺的烷基化反应;重氮酮与环丙烯的分子内环加成环戊酮;顺式-α,β不饱和酯;不饱和醚;δ内酯;手性环戊酮;分子内buchner反应;加氢甲酰化;苄基酮;环化- α-重氮苯乙酮的环加成反应手性3,3-二取代环戊酮;分子内碳氢键插入;氧烷和氧烷;呋喃基重氮酮的环丙烷化反应β-lactams;α-硅酯或酮;重氮酮环化制备氢偶氮酮氧多环的环化/环加成途径;2, 5-disubstituted 3 (2 h) -furanones;呋喃;carbenoid-monothiophthalimide耦合;n -亚硝基酰胺重排;环庚三烯酮;α-重氮酮与炔烃的反应(+)-灰黄霉素(3)的合成环重氮-1,3-二羰基与芳基杂环的反应三环dihydropyrrolizines;与环丙烯的反应;α烷氧基酯;插入到SiH键;heterocyclization;silylformylation;carbenoid插入;摘要总结;杂环化合物;共轭烯酮;加氢甲酰化;carbenoid插入;重组;四元环;diheterobicycloalkanes;[3 + 2]环加成;沃尔夫重排;三元环;五元环;碳氢键插入;重排;1-acetoxyazulenes;耦合;transylidation;债券插入;bicyclization;苄醇;N-sulfonylcarboxamides;异构化;芳基化;CH键插入;NH键插入;无键插入;环化;铼(七)氧化;Rh/氧化铝催化剂加氢;铑-铁;铑锑酸(I);水合氯化钌
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