Structural Properties of Nanoparticles TiO2/PVA Polymeric Films

Samara A. Madhloom
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Abstract

In this research, X-ray diffraction of the powder (PVA polymer, titanium dioxide with two parti-cle sizes) and (TiO2 (15.7 nm)/PVA and TiO2 (45.7 nm)/PVA) films have been studied,the amount of polymer is (0.5) g and (0.01)g from each particle sizes of nanoparticles will be used. Casting method is used to prepare homogeneous films on glass petri dishes. All parameters ac-counted for the X-ray diffraction; full width half maximum (FWHM), Miller indices (hkl), size of crystalline (D), Specific Surface Area (S) and Dislocation Density (δ). The nature of the structural of materials and films will be investigated. The XRD pattern of PVA polymer has semi-crystalline nature and the titanium dioxide with two particle sizes have crystalline structure; ana-tase type. While the mixture between these materials led to appearing some crystalline peaks into XRD pattern of PVA polymer
纳米TiO2/PVA聚合物薄膜的结构特性
在本研究中,对粉末(PVA聚合物,二氧化钛具有两种粒径)和(TiO2 (15.7 nm)/PVA和TiO2 (45.7 nm)/PVA)薄膜进行了x射线衍射研究,聚合物的用量分别为(0.5)g和(0.01)g,每种粒径的纳米颗粒将被使用。采用浇铸法在玻璃培养皿上制备均匀膜。对x射线衍射的所有参数进行了计算;全宽半最大值(FWHM),米勒指数(hkl),晶体尺寸(D),比表面积(S)和位错密度(δ)。材料和薄膜的结构性质将被研究。PVA聚合物的XRD谱图具有半结晶性质,两种粒径的二氧化钛均具有结晶结构;ana-tase类型。而这些材料的混合使得PVA聚合物的XRD图中出现了一些结晶峰
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