Preparation of PVA/PEG Phase Change Composite Nanofibers by Electrospinning

D. Sun, T. Xu, Y. Liu, Mei Zhang
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引用次数: 8

Abstract

Phase change PVA / PEG composite nanofibers were prepared by electrospinning, micro-morphology of PVA / PEG fibers with different weight content were analyzed, the phase change characteristics were also analyzed. The result showed that well distributed composite nanofibers which composed by PVA/PEG blend solution can be obtained by electrospinning.PVA fibreforming were influenced because of the existence of PEG, including bond, irregular block, small rough, uneven diameter distribution in fibers. PVA/PEG blend solution of 4:6 weight content was well fibreforming compared with other different weight content.The continuity of spinneret flow in electrospinning would directly affected by polymer solution consentrition and viscosity. Further research about which and the influence in fibers diameter and morphology will be explored. Composite nanofibers possessed reversible phase transition characteristics,Tm Essentially unchanged ,Tcwere related to the weight percentage of PEG/PVA, at the same time, the enthalpy will increase along with the gradually increase in weight percentage of PEG.
静电纺丝法制备PVA/PEG相变复合纳米纤维
采用静电纺丝法制备了相变PVA / PEG复合纳米纤维,分析了不同重量含量的PVA / PEG纤维的微观形貌,并分析了相变特性。结果表明,静电纺丝可以得到分布均匀的PVA/PEG共混溶液复合纳米纤维。聚乙二醇的存在影响了聚乙烯醇成纤维的形成,包括纤维中的粘结、不规则块状物、小粗糙、直径分布不均匀等。与其他重量含量相比,重量含量为4:6的PVA/PEG共混溶液具有较好的成纤维性。静电纺丝过程中喷丝板流动的连续性直接受到聚合物溶液配比和粘度的影响。我们将进一步研究其对纤维直径和形态的影响。复合纳米纤维具有可逆相变特性,Tm基本不变,tc与PEG/PVA的重量百分比有关,同时焓随PEG重量百分比的逐渐增加而增大。
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