J.G.H. Du Preez, B.J.A.M. Van Brecht, R.F. Van de Water, M.R. Caira
{"title":"The coordination chemistry of divalent cobalt, nickel and copper—IX","authors":"J.G.H. Du Preez, B.J.A.M. Van Brecht, R.F. Van de Water, M.R. Caira","doi":"10.1016/0022-1902(81)80538-6","DOIUrl":null,"url":null,"abstract":"<div><p>The preparation, properties and X-ray crystal structure of [Cu(ttda)(tmen)](ClO<sub>4</sub>)<sub>2</sub>, a complex of divalent copper perchlorate with the ligands N,N,N′,N′-tetramethyl-1,2-diaminoethane (tmen) and bis-(N,N′-dimethyl-acetamido)thioether(ttda) are reported. The crystals are monoclinic with <em>a</em> = 15.35(1), <em>b</em> = 15.04(1), <em>c</em> = 10.91(1) A, β = 98.74(2)°, four formula units per unit cell and space group P2<sub>1</sub>/<em>n</em>. The complex cation is shown to be penta-coordinate with a distorted square pyramidal geometry. Comparison is made with the properties and structure of the previously reported CuCl<sub>2</sub>·ttda.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 9","pages":"Pages 2011-2016"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80538-6","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281805386","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
The preparation, properties and X-ray crystal structure of [Cu(ttda)(tmen)](ClO4)2, a complex of divalent copper perchlorate with the ligands N,N,N′,N′-tetramethyl-1,2-diaminoethane (tmen) and bis-(N,N′-dimethyl-acetamido)thioether(ttda) are reported. The crystals are monoclinic with a = 15.35(1), b = 15.04(1), c = 10.91(1) A, β = 98.74(2)°, four formula units per unit cell and space group P21/n. The complex cation is shown to be penta-coordinate with a distorted square pyramidal geometry. Comparison is made with the properties and structure of the previously reported CuCl2·ttda.
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