{"title":"X-ray absorption near-edge structure (XANES) spectroscopy","authors":"G. Henderson, F. Groot, B. Moulton","doi":"10.2138/RMG.2014.78.3","DOIUrl":null,"url":null,"abstract":"The previous Reviews in Mineralogy volume on spectroscopic methods (Vol. 18 Spectroscopic Methods in Mineralogy and Geology , Frank C. Hawthorne, ed. 1988), contained a single chapter on X-ray absorption spectroscopy which reviewed aspects of both EXAFS (Extended X-ray Absorption Fine Structure) and XANES (X-ray Absorption Near-Edge Structure) (Brown et al. 1988, Chapter 11) However, since publication of that review there have been considerable advances in our understanding of XANES theory and applications. Hence EXAFS and XANES have been separated into their own individual chapters in the current volume. In this chapter we endeavor to bring the reader up to date with regard to current XANES theories, as well as, introducing them to the common applications of the technique in mineralogy, geochemistry and materials science. There have been several reviews of XANES (cf., Brown et al. 1988, Brown and Parks 1989, Manceau et al. 2002, Brown and Sturchio 2002, Mottana 2004, Rehr and Ankudinov 2005, de Groot 2001, 2005, and papers therein). In this chapter on XANES it is not our intention to provide a comprehensive review of all the XANES studies since 1988 but to summarize what X-ray edges are commonly investigated and what one can expect to be able to extract from the data. The reader is also advised to read the chapters in this volume on analytical transmission electron microscopy by Brydson et al. (2014, this volume) where (core level) electron energy loss (EELS) spectroscopy is discussed, and by Lee et al. (2014, this volume) on X-ray Raman spectroscopy (XRS), as these techniques provide element specific information similar to XANES. X-ray absorption near-edge structure (XANES) spectroscopy using synchrotron radiation is a well-established technique providing information on the electronic, structural and magnetic properties of matter. In XANES, …","PeriodicalId":49624,"journal":{"name":"Reviews in Mineralogy & Geochemistry","volume":"158 1","pages":"75-138"},"PeriodicalIF":0.0000,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"215","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reviews in Mineralogy & Geochemistry","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.2138/RMG.2014.78.3","RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Earth and Planetary Sciences","Score":null,"Total":0}
引用次数: 215
Abstract
The previous Reviews in Mineralogy volume on spectroscopic methods (Vol. 18 Spectroscopic Methods in Mineralogy and Geology , Frank C. Hawthorne, ed. 1988), contained a single chapter on X-ray absorption spectroscopy which reviewed aspects of both EXAFS (Extended X-ray Absorption Fine Structure) and XANES (X-ray Absorption Near-Edge Structure) (Brown et al. 1988, Chapter 11) However, since publication of that review there have been considerable advances in our understanding of XANES theory and applications. Hence EXAFS and XANES have been separated into their own individual chapters in the current volume. In this chapter we endeavor to bring the reader up to date with regard to current XANES theories, as well as, introducing them to the common applications of the technique in mineralogy, geochemistry and materials science. There have been several reviews of XANES (cf., Brown et al. 1988, Brown and Parks 1989, Manceau et al. 2002, Brown and Sturchio 2002, Mottana 2004, Rehr and Ankudinov 2005, de Groot 2001, 2005, and papers therein). In this chapter on XANES it is not our intention to provide a comprehensive review of all the XANES studies since 1988 but to summarize what X-ray edges are commonly investigated and what one can expect to be able to extract from the data. The reader is also advised to read the chapters in this volume on analytical transmission electron microscopy by Brydson et al. (2014, this volume) where (core level) electron energy loss (EELS) spectroscopy is discussed, and by Lee et al. (2014, this volume) on X-ray Raman spectroscopy (XRS), as these techniques provide element specific information similar to XANES. X-ray absorption near-edge structure (XANES) spectroscopy using synchrotron radiation is a well-established technique providing information on the electronic, structural and magnetic properties of matter. In XANES, …
之前的矿物学光谱方法评论卷(第18卷矿物学和地质学中的光谱方法,Frank C. Hawthorne, 1988年编)包含了一个关于x射线吸收光谱的单独章节,该章节回顾了EXAFS(扩展x射线吸收精细结构)和XANES (x射线吸收近边缘结构)(Brown等人,1988年,第11章)。自该评论发表以来,我们对XANES理论和应用的理解取得了相当大的进展。因此,EXAFS和XANES在本卷中被分成各自的章节。在本章中,我们努力使读者了解当前XANES理论的最新情况,并向他们介绍该技术在矿物学,地球化学和材料科学中的常见应用。关于XANES已有几篇综述(参见Brown et al. 1988, Brown and Parks 1989, Manceau et al. 2002, Brown and Sturchio 2002, Mottana 2004, Rehr and Ankudinov 2005, de Groot 2001, 2005,以及其中的论文)。在关于XANES的这一章中,我们的意图不是提供自1988年以来所有XANES研究的全面回顾,而是总结通常调查的x射线边缘以及人们可以期望能够从数据中提取的内容。还建议读者阅读本卷中Brydson等人(2014年,本卷)关于分析透射电子显微镜的章节,其中讨论了(核心水平)电子能量损失(EELS)光谱,以及Lee等人(2014年,本卷)关于x射线拉曼光谱(XRS)的章节,因为这些技术提供了类似于XANES的元素特定信息。使用同步辐射的x射线吸收近边结构(XANES)光谱是一种成熟的技术,可以提供有关物质的电子,结构和磁性质的信息。在XANES中,…
期刊介绍:
RiMG is a series of multi-authored, soft-bound volumes containing concise reviews of the literature and advances in theoretical and/or applied mineralogy, crystallography, petrology, and geochemistry. The content of each volume consists of fully developed text which can be used for self-study, research, or as a text-book for graduate-level courses. RiMG volumes are typically produced in conjunction with a short course but can also be published without a short course. The series is jointly published by the Mineralogical Society of America (MSA) and the Geochemical Society.