The wavelength dependence of the photo-oxidation of CH2O

Jayant Desai, Julian Heicklen
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Abstract

The photo-oxidation of CH2O in excess O2 was studied at 253.7, 280.3, 312.8 and 326.1 nm at 25 °C. At all wavelengths except 253.7 nm, Φ(CO) = 1.0. At 253.7 nm, Φ(CO) = 0.77. The molecular photodecomposition is given by Φ(H2), which is 0.28, 0.28, 0.16 and 0.40 respectively at the four wavelengths.

CH2O光氧化的波长依赖性
在253.7、280.3、312.8和326.1 nm波长下,研究了CH2O在过量O2中的光氧化反应。在253.7 nm以外的所有波长,Φ(CO) = 1.0。在253.7 nm处,Φ(CO) = 0.77。分子光分解由Φ(H2)给出,在四个波长下分别为0.28、0.28、0.16和0.40。
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