V. Vidal, A. Théolier, J. Thivolle-cazat, J. Basset
{"title":"Activation and functionalisation of the C–H bonds of methane and higher alkanes by a silica-supported tantalum hydride complex","authors":"V. Vidal, A. Théolier, J. Thivolle-cazat, J. Basset","doi":"10.1039/C39950000991","DOIUrl":null,"url":null,"abstract":"Silica-supported tantalum hydride activates at low temperature the C–H and the C–D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":"6 1","pages":"991-992"},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"23","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950000991","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 23
Abstract
Silica-supported tantalum hydride activates at low temperature the C–H and the C–D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.