{"title":"Lipase-catalyzed kinetic resolution of 4-hydroxy-5-dodecynonitrile and its application to facile synthesis of a cupreous chafer beetle sex pheromone","authors":"Ei-Ichiro Fukusaki , Shiro Satoda , Shuji Senda , Tetsuo Omata","doi":"10.1016/S0922-338X(98)80161-X","DOIUrl":null,"url":null,"abstract":"<div><p>A facile synthetic method for a cupreous chafer beetle sex pheromone (<em>R,Z</em>)-(−)-5-(1-octenyl)oxacyclopentan-2-one has been developed by employing lipase-catalyzed enantioselective acylation of racemic 4-hydroxy-5-dodecynonitrile in an organic solvent.</p></div>","PeriodicalId":15696,"journal":{"name":"Journal of Fermentation and Bioengineering","volume":"86 5","pages":"Pages 508-509"},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0922-338X(98)80161-X","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fermentation and Bioengineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0922338X9880161X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
A facile synthetic method for a cupreous chafer beetle sex pheromone (R,Z)-(−)-5-(1-octenyl)oxacyclopentan-2-one has been developed by employing lipase-catalyzed enantioselective acylation of racemic 4-hydroxy-5-dodecynonitrile in an organic solvent.
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