A.Noman M.M. Rahman, Roger Bishop, Donald C. Craig, Marcia L. Scudder
{"title":"Inclusion Properties of a Chlorinated Diquinoline Host","authors":"A.Noman M.M. Rahman, Roger Bishop, Donald C. Craig, Marcia L. Scudder","doi":"10.1016/S1472-7862(03)00050-9","DOIUrl":null,"url":null,"abstract":"<div><p>The new lattice inclusion host 6α,13α-dibromo-2,9-dichloro-5bα,6,12bα,13-tetrahydropentaleno[1,2-<em>b</em>:4,5-<em>b</em>′]diquinoline <strong>8</strong> was prepared, and found to include far fewer guests than its non-chlorinated analogue <strong>2</strong>. Compounds (<strong>8</strong>)<sub>2</sub>·(ethyl acetate) and (<strong>8</strong>)<sub>2</sub>·(benzene) form molecular pen and staircase inclusion compounds respectively. Their X-ray structures are analysed and compared in crystal engineering terms.</p></div>","PeriodicalId":100833,"journal":{"name":"Journal of Supramolecular Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2002-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1472-7862(03)00050-9","citationCount":"6","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Supramolecular Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1472786203000509","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 6
Abstract
The new lattice inclusion host 6α,13α-dibromo-2,9-dichloro-5bα,6,12bα,13-tetrahydropentaleno[1,2-b:4,5-b′]diquinoline 8 was prepared, and found to include far fewer guests than its non-chlorinated analogue 2. Compounds (8)2·(ethyl acetate) and (8)2·(benzene) form molecular pen and staircase inclusion compounds respectively. Their X-ray structures are analysed and compared in crystal engineering terms.
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