FONTES DE MATÉRIA ORGÂNICA PARA OS SEDIMENTOS SUPERFICIAIS DO ESTUÁRIO DO RIO ITAPICURU (BAHIA - BRASIL)

IF 0.5 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
J. Santana, Iasmim Leal, Antônio Queiroz, Henrique Assumpção, J. D. De Souza, M. Zucchi, Ana de Albergaria-Barbosa
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Abstract

ORGANIC MATTER SOURCES TO THE SUPERFICIAL SEDIMENT OF THE ITAPICURU RIVER ESTUARY (BAHIA - BRAZIL). The present study evaluated the sources of organic matter (O.M.) in the Itapicuru River estuary (IRE), which is in an environmentally protected area surrounded by the Atlantic Rainforest in the northeast of Brazil. Eleven sediment samples were collected along the study area. Total organic carbon (TOC) and the δ13C values were determined using an elemental analyzer coupled with an isotope ratio mass spectrometer. The n-alkanes composition was evaluated through gas chromatography coupled to a flame ionization detector. TOC and total n-alkanes concentrations ranged, respectively, from not detected to 0.72%, and from lower the limit of detection to 5024 ng g-1. There was a significant concentration of n-C22 and n-C24 in some samples showing bacterial production and recycling of O.M. Values of δ13C ranged from −27.6 to −21.9‰. Carbon preference index, terrestrial-aquatic ratio, aquatic production index, average chain length, and the ratio between n-C29 and n-C31 values ranged, respectively, from 1.42 to 4.11; 2.82 to 9.40; 0.00 to 0.25; 27.7 to 29.9; and 0.27 to 0.43. These results show that concentrations of O.M. to IRE are low, and its main source is C3 plants, such as those from mangroves. There is also the contribution of macrophytes.
伊塔皮库鲁河河口表层沉积物有机质来源(巴伊亚-巴西)
巴西巴伊亚伊塔皮库鲁河河口浅层沉积物有机质来源。本研究对巴西东北部大西洋热带雨林环绕的环境保护区Itapicuru河河口(IRE)的有机质来源进行了评价。沿研究区收集了11个沉积物样本。总有机碳(TOC)和δ13C的测定采用元素分析仪和同位素比值质谱仪。通过气相色谱法和火焰电离检测器对正构烷烃的组成进行了评价。TOC和总正构烷烃浓度分别从未检测到0.72%,从检测下限到5024 ng g-1。在一些样品中,n-C22和n-C24的浓度显著,表明细菌产生和o.m的再循环,δ13C的值在−27.6 ~−21.9‰之间。碳偏好指数、陆水比、水产生产指数、平均链长和n-C29与n-C31比值的变化范围分别为1.42 ~ 4.11;2.82 - 9.40;0.00 ~ 0.25;27.7 - 29.9;从0.27到0.43。结果表明,土壤中om - IRE浓度较低,主要来源于红树林等C3植物。也有大型植物的贡献。
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来源期刊
Quimica Nova
Quimica Nova 化学-化学综合
CiteScore
1.60
自引率
12.50%
发文量
72
审稿时长
2-4 weeks
期刊介绍: Química Nova publishes in portuguese, spanish and english, original research articles, revisions, technical notes and articles about education in chemistry. All the manuscripts submitted to QN are evaluated by, at least, two reviewers (from Brazil and abroad) of recognized expertise in the field of chemistry involved in the manuscript. The Editorial Council can be eventually asked to review manuscripts. Editors are responsible for the final edition of QN.
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