Darstellung und Reaktivität der Cyclopentadienyl-dicarbonyl-methyl-mangan-Komplexe [C5H5Mn(CO)2(CH3)]− und [C5H5Mn(CO)2(CH3)2]

IF 0.8 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences Pub Date : 1983-01-01 DOI:10.1515/znb-1983-1129

D. Sellmann, P. Klostermann

引用次数: 0

Abstract

Preparation du compose monomethyl par reaction entre −20 et +10°C de CpMn(CO) 2 N 2 avec LiCH 3 dans THF. L'alkylation par [(CH 3 ) 3 O]BF 4 donne le compose dimethyl

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描述和Cyclopentadienyl-dicarbonyl-methyl-mangan-Komplexe [C5H5Mn Reaktivität (CO) 2 (CH3)]−和C5H5Mn (CO) 2 (CH3) 2]

在−20 ~ +10℃CpMn(CO) 2n2与LiCH 3在THF中反应制备单甲基化合物。[(ch3) 3 O] bf4的烷基化得到二甲基化合物

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences 化学-无机化学与核化学

CiteScore

1.80

自引率

12.50%

发文量

期刊介绍： Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur. Topics Solid state chemistry Coordination chemistry Main group element chemistry Organic chemistry Natural product chemistry.