Metallkomplexe von 2,2’-Dipyridyldisulfid mit Quecksilber(II)-, Cadmium(II)- und Zink(II)-Halogeniden und mit Cadmium(II)- Trifluormethansulfonat

IF 0.8 4区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
J. Pickardt, L. V. Chrzanowski, R. Steudel, Marina Borowski, Sebastian Beck
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引用次数: 0

Abstract

Crystals of diiodo-2,2'-dipyridyldisulfide mercury(II) [HgI 2 (C 5 H 4 N) 2 S 2 ], dichloro-2,2'-dipyridyldisulfide zinc(II) [ZnCl 2 (C 5 H 4 N) 2 S 2 ], dibromo-2,2'-dipyridyldisulfide cadmium(II) [CdBr 2 (C 5 H 4 N) 2 S 2 ], diiodo-2,2'-dipyridyldisulfide cadmium(II) [CdI 2 (C 5 H 4 N) 2 S 2 ], and diaquo 2,2'-dipyridyldisulfide cadmium(II) trifluoromethanesulfonate [Cd(H 2 O) 2 (C 5 H 4 N) 2 S 2 ](CF 3 SO 3 ) 2 , were obtained by evaporation of solutions of the ligand and the appropriate metal salts, and their X-ray crystal structures determined.
turner含汞的22个氢化硫镉(II),镉(II)和锌(II)镉和镉(II)诱导甲烷
diiodo-2晶体,2》-dipyridyldisulfide汞(二)[HgI 2 (C 5 H 4 N)负责2 S 2], dichloro-2, 2》-dipyridyldisulfide锌(II) [ZnCl 2 (C 5 H 4 N) 2 S 2], dibromo-2, 2”-dipyridyldisulfide镉(二)[CdBr 2 (C 5 H 4 N) 2 S 2], diiodo-2, 2》-dipyridyldisulfide镉(二)[CdI 2 (C 5 H 4 N) 2 S 2],和diaquo 2, 2’-dipyridyldisulfide镉(二)trifluoromethanesulfonate [Cd (H 2 O) 2 (C 5 H 4 N) 2 S 2] (CF 3 3) 2,由配体和相应的金属盐溶液蒸发得到,并测定了它们的x射线晶体结构。
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来源期刊
CiteScore
1.80
自引率
12.50%
发文量
91
期刊介绍: Zeitschrift fuer Naturforschung B (ZNB) publishes novel research in all areas of inorganic chemistry, organic chemistry, and analytical chemistry. In particular, the journal focuses on solid state chemistry, coordination chemistry, main group element chemistry, synthetic organic chemistry, natural product chemistry and, to a lesser extent, on analytical chemistry. For more than 65 years Zeitschrift fuer Naturforschung B has been open to contributions from all fields of experimental and theoretical chemistry. Zeitschrift fuer Naturforschung B publishes 12 issues per volume/year. Sometimes double issues occur. Topics Solid state chemistry Coordination chemistry Main group element chemistry Organic chemistry Natural product chemistry.
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