The radiation grafting of N-vinyl-2-pyrrolidone to segmented polyetherurethane in alkaline meduim

Ha Hongfei , Pan Yingdong , Wu Jilan , Yang Fuliang , Feng Xinde
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引用次数: 7

Abstract

The gamma radiation grafting of N-vinyl-2-pyrrolidone (N-VP) to segmented polyetherurethane (SPEU) was studied.

The grafting was performed by the preswelling technique. In this work the experiments of the polymer films preswollen in N-VP-aqueous solution with different acidity and basicity showed that the radiation grafting only occured in the basic medium.

The influence of temperature, swelling degree in the basic monomer aqueous solutions and irradiation time at constant dose rate on the grafting yield were investigated.

The swelling behavior of the modified films in water was followed. The penetration of the N-VP into the SPEU was studied by using absorption kinetics and its surface structure was observed by scanning electron microscope. The thrombo- resistance test of the film also has been performed. All the results showed that this grafting procedure was successful.

n -乙烯基-2-吡咯烷酮在碱性介质中辐射接枝到聚聚氨酯
研究了n -乙烯基-2-吡咯烷酮(N-VP)与节段聚聚氨酯(SPEU)的γ辐射接枝反应。采用预膨胀技术进行接枝。在不同酸度和碱度的n - vp水溶液中对聚合物薄膜进行了预膨胀实验,结果表明,辐射接枝只发生在碱性介质中。研究了温度、在碱性单体水溶液中的溶胀程度和等剂量率辐照时间对接枝率的影响。研究了改性膜在水中的溶胀行为。利用吸收动力学研究了N-VP对SPEU的渗透,并用扫描电镜观察了其表面结构。并对膜进行了凝血阻力试验。结果表明,移植手术是成功的。
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