Reactive surfactants in heterophase polymerization

A. Guyot, K. Tauer, J.M. Asua, S. Van Es, C. Gauthier, A.C. Hellgren, D.C. Sherrington, A. Montoya-Goni, M. Sjoberg, O. Sindt, F. Vidal, M. Unzue, H. Schoonbrood, E. Shipper, P. Lacroix-Desmazes
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引用次数: 140

Abstract

This paper summarizes the work carried out during 3 years in a Network of the program “Human Capital and Mobility” of the European Union CHRX 93-0159 entitled “Reactive surfactants in heterophase polymerization for high performance polymers”. A series of about 25 original papers will be published in the open literature under the general title of this feature article from Part I to Part XXV. The synthesis of selected surfactants either anionic or non ionic, and as well inisurfs (both initiators and surfactants), transurfs (both transfer agent and surfactants) or surfmers (both comonomers and surfactants) is shortly described. They were applied in emulsion polymerization and dispersion polymerization, and their behavior in shortly discussed. Finally films have been produced from a few of them, mainly from surfmer with maleic reactivity, and the main properties, and interests of such films are discussed.

异相聚合反应性表面活性剂
本文总结了欧盟CHRX 93-0159题为“高性能聚合物异相聚合中的活性表面活性剂”的“人力资本和流动性”计划网络3年来所进行的工作。从第一部分到第二十五部分,一系列约25篇原创论文将以本专题文章的总标题发表在开放文献中。本文简要介绍了所选择的阴离子或非离子表面活性剂的合成,以及引发剂(引发剂和表面活性剂)、转移剂(转移剂和表面活性剂)或表面活性剂(共聚单体和表面活性剂)的合成。将其应用于乳液聚合和分散聚合,并对其性能进行了简要讨论。最后介绍了几种具有马来酸反应性的薄膜的制备方法,并对这些薄膜的主要性质和研究方向进行了讨论。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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