Synthesis of multi-hybrid hemicucurbiturils

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of Inclusion Phenomena and Macrocyclic Chemistry Pub Date : 2023-01-17 DOI:10.1007/s10847-022-01176-9

Xiaoting Yuan, Qingkai Zeng, Li Wang, Yuting You, Xingbao Cen, Qianjun Zhang, Qingmei Ge, Hang Cong, Mao Liu

引用次数: 0

Abstract

A novel multi-hybrid hemicucurbituril with good solubility in organic solvent has been synthesized by combining derived glycoluril, ethyleneurea, and aromatic group in one macrocycle. This macrocycle has exhibited properties in photoresponse and derivatization, and showed obvious interaction with Fe³⁺ and Cu²⁺ by the fluorescence spectra study. The modified hemicucurbituril could be easily converted to another imidazolidine-2,4-dione-containing macrocycle.

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多杂化半脲类化合物的合成

将衍生的乙二醇脲、乙烯脲和芳香族在一个大环上结合，合成了一种具有良好溶解度的新型多杂化半脲脲。该大环具有光响应和衍生化性质，荧光光谱研究表明与Fe3+和Cu2+有明显的相互作用。改性后的半脲类化合物可以很容易地转化为另一种含2,4-二酮的咪唑烷大环。

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来源期刊

Journal of Inclusion Phenomena and Macrocyclic Chemistry Agricultural and Biological Sciences-Food Science

CiteScore

4.10

自引率

8.70%

发文量

期刊介绍： The Journal of Inclusion Phenomena and Macrocyclic Chemistry is the premier interdisciplinary publication reporting on original research into all aspects of host-guest systems. Examples of specific areas of interest are: the preparation and characterization of new hosts and new host-guest systems, especially those involving macrocyclic ligands; crystallographic, spectroscopic, thermodynamic and theoretical studies; applications in chromatography and inclusion polymerization; enzyme modelling; molecular recognition and catalysis by inclusion compounds; intercalates in biological and non-biological systems, cyclodextrin complexes and their applications in the agriculture, flavoring, food and pharmaceutical industries; synthesis, characterization and applications of zeolites. The journal publishes primarily reports of original research and preliminary communications, provided the latter represent a significant advance in the understanding of inclusion science. Critical reviews dealing with recent advances in the field are a periodic feature of the journal.