Metal–organic framework-derived single-atom catalysts for peroxymonosulfate-mediated organic wastewater remediation

IF 8 2区 工程技术 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY
Haitao Li , Jian Liu
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引用次数: 2

Abstract

As an emerging area, single-atom catalysts (SACs), in the past decade, have sparked tremendous research interests in various fields due to maximum atom utilization and excellent catalytic activity. Recently, SACs have been extended to peroxymonosulfate (PMS)-mediated advanced oxidation processes for organic wastewater remediation. In the current perspective, we first briefly overviewed typical synthetic methods and characterization techniques for metal–organic framework (MOF)-derived SACs. Then, we highlighted the degradation applications of various refractory organic pollutants via SAC/PMS systems. Subsequently, the catalytic mechanisms as well as the variety of reactive species were discussed. Finally, we proposed several future development directions for MOF-based SACs in environmental remediation.

Abstract Image

金属有机骨架衍生的单原子催化剂用于过氧单硫酸盐介导的有机废水修复
单原子催化剂作为一个新兴的领域,由于其最大的原子利用率和优异的催化活性,在近十年来引起了各个领域的极大研究兴趣。最近,SACs已扩展到过氧单硫酸盐(PMS)介导的高级氧化工艺中,用于有机废水的修复。从目前的角度来看,我们首先简要概述了金属有机骨架(MOF)衍生sac的典型合成方法和表征技术。重点介绍了SAC/PMS系统对各种难降解有机污染物的降解应用。随后,讨论了催化机理以及反应物质的种类。最后,提出了基于mof的sac在环境修复中的未来发展方向。
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来源期刊
Current Opinion in Chemical Engineering
Current Opinion in Chemical Engineering BIOTECHNOLOGY & APPLIED MICROBIOLOGYENGINE-ENGINEERING, CHEMICAL
CiteScore
12.80
自引率
3.00%
发文量
114
期刊介绍: Current Opinion in Chemical Engineering is devoted to bringing forth short and focused review articles written by experts on current advances in different areas of chemical engineering. Only invited review articles will be published. The goals of each review article in Current Opinion in Chemical Engineering are: 1. To acquaint the reader/researcher with the most important recent papers in the given topic. 2. To provide the reader with the views/opinions of the expert in each topic. The reviews are short (about 2500 words or 5-10 printed pages with figures) and serve as an invaluable source of information for researchers, teachers, professionals and students. The reviews also aim to stimulate exchange of ideas among experts. Themed sections: Each review will focus on particular aspects of one of the following themed sections of chemical engineering: 1. Nanotechnology 2. Energy and environmental engineering 3. Biotechnology and bioprocess engineering 4. Biological engineering (covering tissue engineering, regenerative medicine, drug delivery) 5. Separation engineering (covering membrane technologies, adsorbents, desalination, distillation etc.) 6. Materials engineering (covering biomaterials, inorganic especially ceramic materials, nanostructured materials). 7. Process systems engineering 8. Reaction engineering and catalysis.
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