New crystal structures of alkali metal tetrakis(pentafluorophenyl)borates

IF 1.8 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Main Group Metal Chemistry Pub Date : 2020-01-01 DOI:10.1515/mgmc-2020-0011

Daniel Duvinage, Artem Schröder, E. Lork, J. Beckmann

引用次数: 0

Abstract

Abstract The crystal structures of the salts [Li(1,2-F2C6H4)] [B(C6F5)4] (1) and Cs[B(C6F5)4] (2) comprise six Li···F contacts (1.965(3) − 2.312(3) Å) and twelve Cs···F contacts (3.0312(1) − 3.7397(2) Å), respectively, which are significantly shorter than the sum of van der Waals radii (3.29 and 4.90 Å).

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碱金属四(五氟苯)硼酸盐的新晶体结构

[Li(1,2- f2c6h4)] [B(C6F5)4](1)和Cs[B(C6F5)4](2)的晶体结构分别由6个Li···F触点(1.965(3)−2.312(3)Å)和12个Cs···F触点(3.0312(1)−3.7397(2)Å)组成，明显短于van der Waals半径之和(3.29和4.90 Å)。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Main Group Metal Chemistry CHEMISTRY, INORGANIC & NUCLEAR-CHEMISTRY, ORGANIC

CiteScore

4.10

自引率

27.80%

发文量

审稿时长

4 weeks

期刊介绍： This journal is committed to the publication of short communications, original research, and review articles within the field of main group metal and semi-metal chemistry, Main Group Metal Chemistry is an open-access, peer-reviewed journal that publishes in ongoing way. Papers addressing the theoretical, spectroscopic, mechanistic and synthetic aspects of inorganic, coordination and organometallic main group metal and semi-metal compounds, including zinc, cadmium and mercury are welcome. The journal also publishes studies relating to environmental aspects of these metals, their toxicology, release pathways and fate. Articles on the applications of main group metal chemistry, including in the fields of polymer chemistry, agriculture, electronics and catalysis, are also accepted.