Upgrading of Sharqy Baghdad Heavy Oil via N-Hexane Solvent

Firdews Shakir, H. Hussein, Zeinab T. Abdulwahhab
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引用次数: 1

Abstract

   Asphaltenes are a solubility class described as a component of crude oil with undesired characteristics. In this study, Sharqy Baghdad heavy oil upgrading was achieved utilizing the solvent deasphalting approach as asphaltenes are insoluble in paraffinic solvents; they may be removed from heavy crude oil by adding N-Hexane as a solvent to create deasphalted oil (DAO)of higher quality. This method is known as Solvent De-asphalting (SDA). Different effects have been assessed for the SDA process, such as solvent to oil ratio (4-16/1 ml/g), the extraction temperature (23 ºC) room temperature and (68 ºC) reflux temperature at (0.5 h mixing time with 400 rpm mixing speed). The best solvent deasphalting results were obtained at room temperature and 12 ml/g solvents to oil ratio. As a result, the API of DAO was increased by 9.3º compared to the API of  Sharqy Baghdad heavy oil. The asphaltene reduction was 61.56%. The Sulfur removal was 32.8%, the Vanadium removal was 36.48%, and the Nickel removal was 46.21%.
Sharqy巴格达重油正己烷溶剂提质
沥青质是一种溶解度高的原油成分,具有不期望的特性。在本研究中,由于沥青质不溶于石蜡溶剂,采用溶剂脱沥青方法实现了Sharqy Baghdad重油的提质;它们可以通过加入正己烷作为溶剂从重质原油中去除,从而产生更高质量的脱沥青油(DAO)。这种方法被称为溶剂脱沥青(SDA)。对SDA工艺的不同影响进行了评估,如溶剂与油比(4-16/1 ml/g)、提取温度(23℃)室温和回流温度(68℃)(混合时间0.5 h,混合转速400 rpm)。在室温和溶剂油比为12 ml/g条件下,溶剂脱沥青效果最佳。结果,DAO的API比Sharqy Baghdad重油的API提高了9.3º。沥青质还原率为61.56%。硫去除率为32.8%,钒去除率为36.48%,镍去除率为46.21%。
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