Heterotridentate organodiphosphines in Pt(η3–P1X1P2)(Y) derivatives-structural aspects

IF 4.1 3区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Reviews in Inorganic Chemistry Pub Date : 2021-07-22 DOI:10.1515/revic-2021-0011

M. Melnik, P. Mikuš

引用次数: 3

Abstract

Abstract This review covers over 30 examples of monomeric Pt(II) complexes of the types: Pt(η3–P1O1P2)(Y) (Y = PL, CL, OL), Pt(η3–P1N1P2)(Y) (Y = H, NL, CL, Cl, PL) and Pt(η3–P1P2N1)(Y) (Y = Cl). The heterotridentate donor ligands create 11 types of a couple chelate rings with common central atom O1 (η3–P1O1P2), N1 (η3–P1N1P2) and P2 (η3–P1P2N1). The most frequent is P1C2N1C2P2. Some cooperative effects between chelate rings and Y donor ligands were found and discussed. A degree of distortions of square-planar geometry about Pt(II) were also calculated.

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Pt(η3-P1X1P2)(Y)衍生物中的异三齿有机二膦-结构方面

摘要本文综述了30多个单体Pt(II)配合物的类型:Pt(η3 - p1p2p2)(Y) (Y = PL, CL, OL)， Pt(η3-P1N1P2)(Y) (Y = H, NL, CL, CL, PL)和Pt(η3-P1P2N1)(Y) (Y = CL)。杂三齿配体形成11种由共同中心原子O1 (η3-P1N1P2)、N1 (η3-P1N1P2)和P2 (η3-P1P2N1)组成的对螯合环。最常见的是P1C2N1C2P2。发现并讨论了螯合环与Y供体配体之间的协同效应。还计算了Pt(II)的方平面几何变形程度。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Reviews in Inorganic Chemistry 化学-分析化学

CiteScore

7.30

自引率

4.90%

发文量

审稿时长

1 months

期刊介绍： Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids