Synthesis and characterization of cobalt SCS pincer complexes.

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Monatshefte Fur Chemie Pub Date : 2022-01-01 Epub Date: 2022-07-16 DOI:10.1007/s00706-022-02949-1

Jan Pecak, Matthias Käfer, Sarah Fleissner, Werner Artner, Karl Kirchner

引用次数: 0

Abstract

The synthesis and characterization of two Co(II) complexes stabilized by a tridentate SCS pincer ligand are described. Paramagnetic [Co(κ³-SCS^CH2-Et)₂] and [Co(κ³-SCS^CH2-tBu)(κ²-SCS^CH2-tBu)] were obtained via transmetalation protocol from CoBr₂ and S(C-Br)S^CH2-R (R = Et, tBu). Oxidation of the latter with [Cp₂Fe]PF₆ affords the diamagnetic 18 VE complex [Co(κ³-SCS^CH2-tBu)₂]PF₆. X-ray structures and DFT calculations are presented.

Graphical abstract:

Supplementary information: The online version contains supplementary material available at 10.1007/s00706-022-02949-1.

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钴 SCS 钳子复合物的合成与表征。

本文介绍了由三叉 SCS 锌配体稳定的两种 Co(II) 复合物的合成和表征。顺磁性[Co(κ3-SCSCH2-Et)2]和[Co(κ3-SCSCH2-tBu)(κ2-SCSCH2-tBu)]是由 CoBr2 和 S(C-Br)SCH2-R（R = Et，tBu）通过反金属化协议得到的。后者与[Cp2Fe]PF6 氧化后得到二磁性 18 VE 复合物[Co(κ3-SCSCH2-tBu)2]PF6。图文摘要：补充信息：在线版本包含补充材料，可查阅 10.1007/s00706-022-02949-1。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Monatshefte Fur Chemie 化学-化学综合

CiteScore

3.70

自引率

5.60%

发文量

116

审稿时长

3.3 months

期刊介绍： "Monatshefte für Chemie/Chemical Monthly" was originally conceived as an Austrian journal of chemistry. It has evolved into an international journal covering all branches of chemistry. Featuring the most recent advances in research in analytical chemistry, biochemistry, inorganic, medicinal, organic, physical, structural, and theoretical chemistry, Chemical Monthly publishes refereed original papers and a section entitled "Short Communications". Reviews, symposia in print, and issues devoted to special fields will also be considered.