A 3D tetrathiafulvalene-based metal–organic framework with intramolecular charge transfer for efficient near-infrared photothermal conversion†

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2023-08-30 DOI:10.1039/D3CC03165A

Yu Zhang, Zi-Wei Xia, Liang-jun Shen, Hao Tang, Xu-Feng Luo, Xing Li and Xunwen Xiao

引用次数: 0

Abstract

The selection of metal centers can endow donor–metal–accepter (D–M–A) type MOFs with progressive framework dimensions. 3D Cd-based MOFs with intramolecular charge transfer caused by D–M–A exhibit a satisfactory photothermal conversion efficiency of 35.7%, with the temperature rapidly rising from 25 °C to 201 °C in 7 s under 808 nm laser irradiation.

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一种具有有效近红外光热转换的分子内电荷转移的三维四硫丁烯基金属有机框架

金属中心的选择可以使供体-金属-受体(D-M-A)型mof具有递进的框架尺寸。由D-M-A引起分子内电荷转移的三维cd基mof在808 nm激光照射下，光热转换效率为35.7%，温度在7 s内从25℃迅速上升到201℃。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.