Visible-light-induced defluorinative carbonylative coupling of alkyl iodides with α-trifluoromethyl substituted styrenes†

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2022-01-01 DOI:10.1039/d2ob00916a

Bo Chen , Kai Yu , Xiao-Feng Wu

引用次数: 0

Abstract

A visible-light-mediated defluorinative carbonylative cross-coupling of alkyl iodides with α-trifluoromethyl styrenes has been developed. The reaction occurs at room temperature under blue light irradiation, and various gem-difluoroalkenes were obtained in moderate to good yields. Synthetic transformations of the obtained product were performed as well.

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可见光诱导碘化烷基与α-三氟甲基取代苯乙烯的脱氟羰基偶联

研究了可见光介导的烷基碘化物与α-三氟甲基苯乙烯的脱氟羰基交叉偶联反应。该反应在室温下蓝光照射下进行，并以中高收率得到了各种宝石二氟烯烃。并对所得产物进行了合成转化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.