Synthesis and Characterization of Novel Ruthenium(II) and Osmium(II) Monodentate Macrocyclic Complexes with Disulfide Linkage

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-12-08 DOI:10.1134/S1070363225605186

J. Kong, X. Bao

引用次数: 0

Abstract

A series of macrocyclic ligands featuring pyridyl functionalization and a disulfide linkage, along with their corresponding ruthenium(II) and osmium(II) complexes, were synthesized and characterized. The monodentate complexes were investigated in both the ‘open’ and ‘closed’ forms. These studies on electron/energy transfer through disulfide linkages provide critical insights for designing future multifunctional metal complexes with enhanced metal-metal interactions.

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新型二硫键单齿钌（II）和锇（II）大环配合物的合成与表征

合成了一系列具有吡啶基功能化和二硫键的大环配体及其相应的钌（II）和锇（II）配合物并对其进行了表征。单齿配合物以“开放”和“封闭”两种形式进行了研究。这些通过二硫键的电子/能量转移的研究为设计未来具有增强金属-金属相互作用的多功能金属配合物提供了重要的见解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.