{"title":"Pressure and temperature dependence of the dielectric properties in barium titanate","authors":"Ali Kiraci, Hamit Yurtseven","doi":"10.1007/s12034-025-03456-9","DOIUrl":null,"url":null,"abstract":"<div><p>Temperature and pressure dependences of the soft-mode frequency (<span>\\(\\omega\\)</span>) and the dielectric constant (<span>\\(\\varepsilon\\)</span>) are studied for the tetragonal-cubic transition (<i>T</i><sub>C</sub> = 395 K) in BaTiO<sub>3</sub>. We find that variations of the frequency and the dielectric constant with the temperature (pressure) are related to each other linearly close to the phase transition in this ferroelectric material. Instead of the Curie-Weiss behaviour of the dielectric constant, the critical behaviour of both soft-mode frequency and the dielectric constant is expressed by the power-law formulae, and the critical exponents are determined using the observed data from the literature. Our predicted frequencies of the soft mode at various pressures and temperatures, can be examined by the experimental measurements close to the tetragonal-cubic transition in BaTiO<sub>3</sub>.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"48 3","pages":""},"PeriodicalIF":2.1000,"publicationDate":"2025-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s12034-025-03456-9","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Temperature and pressure dependences of the soft-mode frequency (\(\omega\)) and the dielectric constant (\(\varepsilon\)) are studied for the tetragonal-cubic transition (TC = 395 K) in BaTiO3. We find that variations of the frequency and the dielectric constant with the temperature (pressure) are related to each other linearly close to the phase transition in this ferroelectric material. Instead of the Curie-Weiss behaviour of the dielectric constant, the critical behaviour of both soft-mode frequency and the dielectric constant is expressed by the power-law formulae, and the critical exponents are determined using the observed data from the literature. Our predicted frequencies of the soft mode at various pressures and temperatures, can be examined by the experimental measurements close to the tetragonal-cubic transition in BaTiO3.
期刊介绍：
The Bulletin of Materials Science is a bi-monthly journal being published by the Indian Academy of Sciences in collaboration with the Materials Research Society of India and the Indian National Science Academy. The journal publishes original research articles, review articles and rapid communications in all areas of materials science. The journal also publishes from time to time important Conference Symposia/ Proceedings which are of interest to materials scientists. It has an International Advisory Editorial Board and an Editorial Committee. The Bulletin accords high importance to the quality of articles published and to keep at a minimum the processing time of papers submitted for publication.
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