Non-isocyanate polyurethane from bio-based feedstocks and their interface applications

Zichen Ling, Liang Gu, Shuzhen Liu, Yuhan Su and Qixin Zhou
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Abstract

Non-isocyanate polyurethane (NIPU) has emerged as a promising material to substitute conventional polyurethane (PU) that relies on toxic precursors—isocyanates. Aligned with the principles of green chemistry, environmental friendliness, and sustainability, NIPU from bio-based materials has gained significant interest in recent years. This review aims to provide a comprehensive overview of NIPU synthesis methods and their various classifications. It also highlights bio-based precursors in NIPU synthesis, supported by detailed case studies. Furthermore, the review explores the potential application of bio-based NIPU at interfaces such as coating, adhesive, and biomedical materials. Finally, the current limitations and perspectives on the development of bio-based NIPU are discussed.

Abstract Image

生物基原料非异氰酸酯聚氨酯及其界面应用
非异氰酸酯聚氨酯(NIPU)已成为替代传统聚氨酯(PU)的一种有前途的材料,传统聚氨酯依赖于有毒的前体-异氰酸酯。符合绿色化学、环境友好和可持续性原则的生物基材料NIPU近年来获得了极大的兴趣。本文综述了NIPU的合成方法及其分类。它还强调了NIPU合成中的生物基前体,并提供了详细的案例研究支持。此外,综述了生物基NIPU在涂层、粘合剂和生物医学材料等界面领域的潜在应用。最后,讨论了目前生物基NIPU的局限性和发展前景。
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