Kinetic-control difunctionalization of olefins to α-hydroxycarbonyls under catalyst-free conditions

IF 9.2 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2025-08-08 DOI:10.1039/d5gc02308d

Hong-Yu Hou , Yuan-Yuan Cheng , Xin-Yu Zhang , Ke Zhang , Hui-Zhen Ren , Kaiyi Su , Zhiyuan Huang , Bin Chen , Chen-Ho Tung , Li-Zhu Wu

引用次数: 0

Abstract

Difunctionalization of olefins is effective in constructing diverse, valuable molecules. However, such a reaction always relies on catalysts to control activity and selectivity. Herein, a catalyst-free difunctionalization of olefins with sulfonyl or alkyl precursors and 1,2-dicarbonyls is reported to synthesize complex α-hydroxycarbonyls under visible light irradiation.

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无催化剂条件下烯烃动力学控制双官能化成α-羟基羰基

烯烃的双官能化是构造多种有价值分子的有效方法。然而，这种反应总是依赖于催化剂来控制活性和选择性。本文报道了在可见光照射下，烯烃与磺酰或烷基前体和1,2-二羰基的无催化剂双官能化反应合成了配合物α-羟基羰基。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.