Hydrothermal Synthesis and Characterization of the Melamine-Based Second-Harmonic Generation Material HgCl2(C3N6H6)

IF 2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Melena Groß, Patrick Schmidt, Carl P. Romao, David Enseling, Thomas Jüstel, Mykhailo Brytskyi, Scott Kroeker, Hans-Jürgen Meyer
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引用次数: 0

Abstract

The pursuit of efficient nonlinear optical materials is critical for advancing optoelectronic applications. This study focuses on the synthesis and characterization of HgCl2(C3N6H6), a melamine-based hybrid metal halide. Structural analysis reveals a non-centrosymmetric lattice facilitated by large asymmetric secondary building units and a π-conjugated system. The compound exhibits a strong second-harmonic generation efficiency. Density functional theory calculations, optical band gap measurements, and photoluminescence measurements specify the electronic properties. For completeness and analytical comparison, the centrosymmetric compound Hg2Cl2(C3N6H6)2 is also introduced.

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三聚氰胺基二次谐波材料HgCl2(C3N6H6)的水热合成及表征
追求高效的非线性光学材料是推进光电应用的关键。本文主要研究了三聚氰胺基杂化金属卤化物HgCl2(C3N6H6)的合成与表征。结构分析揭示了由大型非对称次级建筑单元和π共轭体系促成的非中心对称晶格。该化合物具有较强的二次谐波产生效率。密度泛函理论计算,光学带隙测量和光致发光测量指定电子性质。为了完整性和分析比较,还介绍了中心对称化合物Hg2Cl2(C3N6H6)2。
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来源期刊
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
4.30
自引率
4.30%
发文量
419
审稿时长
1.3 months
期刊介绍: The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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