Ginevra Giobbio, Killian Henault, Gauthier Foucras, Anaïs Prigent, Sylvain Gaillard and Thomas Cailly
{"title":"Chloride-to-(radio)iodide exchange on NHC–metal complexes†","authors":"Ginevra Giobbio, Killian Henault, Gauthier Foucras, Anaïs Prigent, Sylvain Gaillard and Thomas Cailly","doi":"10.1039/D5DT01364J","DOIUrl":null,"url":null,"abstract":"<p >Efficient chloride/iodide exchange on chloro-NHC–metal complexes was achieved under mild conditions using stable or radioactive iodide. The protocol enables simultaneous synthesis of radiolabeled compounds and their non-radioactive references, facilitating the development of chemically matched theranostic pairs.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 31","pages":" 11817-11821"},"PeriodicalIF":3.3000,"publicationDate":"2025-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/dt/d5dt01364j?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/dt/d5dt01364j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Efficient chloride/iodide exchange on chloro-NHC–metal complexes was achieved under mild conditions using stable or radioactive iodide. The protocol enables simultaneous synthesis of radiolabeled compounds and their non-radioactive references, facilitating the development of chemically matched theranostic pairs.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.