Pinaki Nad, Souvik Goswami, Hemanta K. Kisan, Arup Mukherjee
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引用次数: 0
Abstract
A B(C₆F₅)₃-catalyzed desulfurization of thioamides in the presence of phenyl silane has been investigated. Interestingly, thioamides can undergo reduction via two pathways, viz., desulfurization and deamination. In their Research Article (DOI: 10.1002/chem.202500738), H. K. Kisan, A. Mukherjee and co-workers show that despite the possibilities of these two pathways, only one of them is operative selectively to provide the corresponding amines. In the same way, a car (thioamide) has the possibility to turn either right or left along the road; however, a policeman [B(C₆F₅)₃] helps the car to go in the right directions (desulfurization) to avoid the closed road on the left side.
研究了A B（C₆F₅）₃在苯硅烷存在下催化硫酰胺的脱硫。有趣的是，硫胺可以通过两种途径进行还原，即脱硫和脱氨。在他们的研究文章（DOI: 10.1002/chem.202500738）中，H. K. Kisan， A. Mukherjee及其同事表明，尽管有这两种途径的可能性，但其中只有一种是选择性地提供相应的胺。以同样的方式，汽车（硫胺）有可能沿着道路向左或向右转；然而，一名警察[B（C₆F₅）₃]帮助汽车向正确的方向行驶（脱硫），以避免左侧封闭的道路。
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Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields.
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