Mild aerobic oxidation of alcohols to carbonyl compounds with ferric nitrate Nonahydrate in Trifluoroacetic acid

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC

Tetrahedron Letters Pub Date : 2025-06-09 DOI:10.1016/j.tetlet.2025.155687

Yuan Zhang, Zhi-Xin Guo, Pu Zhang

引用次数: 0

Abstract

A facile and effective aerobic oxidation of aromatic, allylic, secondary aliphatic alcohols and diols using a combination of ferric nitrate nonahydrate and trifluoroacetic acid was developed. The expected products were afforded in good to excellent yields. Major advantages of this procedure include room temperature reaction with low energy consumption, the use of cheap and readily available reagents and broad functional group compatibility.

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用硝酸铁在三氟乙酸中轻度有氧氧化制羰基化合物

研究了以非水合硝酸铁和三氟乙酸为溶剂，对芳香族、烯丙基、次生脂肪族醇和二醇进行简单有效的好氧氧化反应。预期产品的产量达到了相当高的水平。该方法的主要优点是室温反应，能耗低，使用廉价易得的试剂，官能团相容性广。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.