Franziska Flecken, Arjun Neyyathala, Toni Grell, Schirin Hanf
{"title":"Outside Front Cover: A Bench-stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application (Angew. Chem. 24/2025)","authors":"Franziska Flecken, Arjun Neyyathala, Toni Grell, Schirin Hanf","doi":"10.1002/ange.202510369","DOIUrl":null,"url":null,"abstract":"<p>The air- and water-stable Ni(0) complex [Ni(PFPh<sub>2</sub>)<sub>4</sub>] is obtained via a unique in-situ reduction and fluorination mechanism from [Ni(MeCN)<sub>4</sub>](BF<sub>4</sub>)<sub>2</sub> and Ph<sub>2</sub>P(═O)─PPh<sub>2</sub>, incorporating typically unstable fluorophosphine ligands. In their Research Article (e202506271), Schirin Hanf et al. demonstrated its utility as a robust Ni(0) source, and showed its superior catalytic activity in coupling reactions compared to the conventional [Ni(COD)<sub>2</sub>].\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 24","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510369","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202510369","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The air- and water-stable Ni(0) complex [Ni(PFPh2)4] is obtained via a unique in-situ reduction and fluorination mechanism from [Ni(MeCN)4](BF4)2 and Ph2P(═O)─PPh2, incorporating typically unstable fluorophosphine ligands. In their Research Article (e202506271), Schirin Hanf et al. demonstrated its utility as a robust Ni(0) source, and showed its superior catalytic activity in coupling reactions compared to the conventional [Ni(COD)2].
通过独特的原位还原和氟化机制，由[Ni(MeCN)4](BF4)2和Ph2P（= O）─PPh2合成了空气和水稳定的Ni（PFPh2）配合物[Ni(PFPh2)4]，其中含有典型的不稳定的氟膦配体。在他们的研究文章（e202506271）中，Schirin Hanf et al.证明了其作为强大的Ni(0)源的实用性，并且与传统的[Ni(COD)2]相比，其在偶联反应中的催化活性更强。
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
