{"title":"Modeling of the Kinetics of Desorption of Dioctyl Phthalate from Polyvinylchloride into Human Blood and Simulation Fluids","authors":"V. G. Nazarov, A. V. Dedov","doi":"10.1134/S1995421224701624","DOIUrl":null,"url":null,"abstract":"<p>A model for the assessment of the kinetics of desorption of dioctyl phthalate from polyvinylchloride films with a coating based on polyurethanes with various compositions into human blood and simulation fluids is proposed. The approach to the modeling of the kinetics of desorption of the plasticizer is based on the equations describing the kinetic dependences of desorption in the system of coordinates of the square root from the time of the process. The proposed model provides determination of the dependence of the kinetics of desorption of the plasticizer on the composition of polyurethane. The delay time of the process of desorption is found and a parameter determining the ratio between the processes of desorption into simulation fluids and blood is proposed.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"18 1","pages":"1 - 5"},"PeriodicalIF":0.5800,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series D","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1995421224701624","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Materials Science","Score":null,"Total":0}
引用次数: 0
Abstract
A model for the assessment of the kinetics of desorption of dioctyl phthalate from polyvinylchloride films with a coating based on polyurethanes with various compositions into human blood and simulation fluids is proposed. The approach to the modeling of the kinetics of desorption of the plasticizer is based on the equations describing the kinetic dependences of desorption in the system of coordinates of the square root from the time of the process. The proposed model provides determination of the dependence of the kinetics of desorption of the plasticizer on the composition of polyurethane. The delay time of the process of desorption is found and a parameter determining the ratio between the processes of desorption into simulation fluids and blood is proposed.
期刊介绍:
Polymer Science, Series D publishes useful description of engineering developments that are related to the preparation and application of glues, compounds, sealing materials, and binding agents, articles on the adhesion theory, prediction of the strength of adhesive joints, methods for the control of their properties, synthesis, and methods of structural modeling of glued joints and constructions, original articles with new scientific results, analytical reviews of the modern state in the field.