Energy-Transfer-Enabled Truce-Smiles Rearrangement Using Sulfonamides as Sulfonyl Radical Precursors.

IF 4.9 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-05-19 DOI:10.1021/acs.orglett.5c01346

Fuyang Yue,Mingxing Li,Jiayi Li,Hongjian Song,Yuxiu Liu,Qingmin Wang

引用次数: 0

Abstract

We have developed a method for visible-light-induced radical Smiles-Truce rearrangement reactions that use sulfonamide-derived imines as sulfonyl radical precursors. This method enables efficient functionalization of alkenes and has the advantages of having a wide substrate scope and not emitting sulfur dioxide, thereby constituting an environmentally friendly approach for the synthesis of structurally complex sulfones, alcohols, and amines.

查看原文本刊更多论文

利用磺酰胺作为磺酰基前体的能量转移激活的休战-微笑重排。

我们已经开发了一种使用磺胺衍生亚胺作为磺酰基前体的可见光诱导自由基smile -休战重排反应的方法。该方法可以实现烯烃的高效功能化，并且具有底物范围广且不排放二氧化硫的优点，从而为合成结构复杂的砜、醇和胺提供了一种环保的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.