Interplanar magnetic exchange in CoPS3.

Abstract

Neutron three-axis spectrometry has been used to determine the interplanar magnetic exchange parameter in the magnetic van der Waals compound CoPS₃. The exchange is found to be small and antiferromagnetic, estimated to be0.020±0.001meV, which is surprising considering that the magnetic structure is correlated ferromagnetically between theabplanes. A possible explanation, involving a small anisotropy in the exchanges, is proposed. The results are discussed with reference to the other members of the transition metal-PS₃compounds.