Flash Communication: S–N Bond Cleavage in Benzisothiazol Affords Complexes Related to [FeFe]-Hydrogenases Active Site with Peptidic-Type Bridge

IF 2.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Organometallics Pub Date : 2025-04-30 DOI:10.1021/acs.organomet.5c0009810.1021/acs.organomet.5c00098

Mohammad J. Uddin, Subas Rajbangshi, Shariff E. Kabir*, Vladimir N. Nesterov, Catherine Elleouet*, Shishir Ghosh* and Philippe Schollhammer*,

引用次数: 0

Abstract

The reaction of [Fe₃(CO)₁₂] with 1,2-benzisothiazol-3(2H)-one affords a route to the di-iron complex [Fe₂(CO)₆(μ-S{C₆H₄}CONH)] (1) featuring a {Fe₂SN} butterfly core with a peptide-like unit in close proximity to the di-iron site. Redox behaviors of 1 and its substituted derivatives [Fe₂(CO)_6-x(PPh₃)_x(μ-S{C₆H₄}CONH)] (x = 1, 2) have been preliminarily investigated.

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闪光通讯：苯并异噻唑中S-N键的断裂提供了与[FeFe]-氢化酶活性位点相关的肽型桥的配合物

[Fe3(CO)12]与1,2-苯并异噻唑-3(2H)- 1的反应提供了一条通往双铁配合物[Fe2(CO)6(μ-S{C6H4}CONH)](1)的途径，该配合物具有一个{Fe2SN}蝴蝶核，其肽样单元靠近双铁位点。初步研究了1及其取代衍生物[Fe2(CO)6-x(PPh3)x(μ-S{C6H4}CONH)] （x = 1,2）的氧化还原行为。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organometallics 化学-无机化学与核化学

CiteScore

5.60

自引率

7.10%

发文量

382

审稿时长

1.7 months

期刊介绍： Organometallics is the flagship journal of organometallic chemistry and records progress in one of the most active fields of science, bridging organic and inorganic chemistry. The journal publishes Articles, Communications, Reviews, and Tutorials (instructional overviews) that depict research on the synthesis, structure, bonding, chemical reactivity, and reaction mechanisms for a variety of applications, including catalyst design and catalytic processes; main-group, transition-metal, and lanthanide and actinide metal chemistry; synthetic aspects of polymer science and materials science; and bioorganometallic chemistry.