One-Pot Microwave-Assisted Olefin Hydroaminomethylation Over Bifunctional Heterogeneous Rh Catalysts

IF 2.3 3区管理学 Q2 ECONOMICS

Journal of Policy Analysis and Management Pub Date : 2025-04-12 DOI:10.1002/cctc.202500268

Fabio Bucciol, Emanuela Calcio Gaudino, Alberto Villa, Maria Carmen Valsania, Silvio Bellomi, Silvia Tabasso, Giancarlo Cravotto, Maela Manzoli

引用次数: 0

Abstract

Heterogeneous lab-made Rh/CNFs gave yield >99% in the one-pot MW-assisted hydroaminomethylation of olefins to amines, using EtOAc as the solvent, due to the synergy between metal and acid surface sites. Acetic acid addition promoted both conversion and selectivity during the rate-determining hydroformylation step.

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微波辅助双功能非均相Rh催化剂上的烯烃氢胺甲基化反应

由于金属和酸性表面位点之间的协同作用，异相实验室制备的Rh/CNFs在一锅微波辅助下，以乙酸乙酯为溶剂，将烯烃氢胺甲基化成胺，产率达到99%。在决定速率的氢甲酰化步骤中，醋酸的加入促进了转化率和选择性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Policy Analysis and Management Multiple-

CiteScore

5.80

自引率

2.60%

发文量

期刊介绍： This journal encompasses issues and practices in policy analysis and public management. Listed among the contributors are economists, public managers, and operations researchers. Featured regularly are book reviews and a department devoted to discussing ideas and issues of importance to practitioners, researchers, and academics.