A. S. Zaguzin, M. A. Bondarenko, N. A. Korobeinikov, A. V. Zaitsev, S. A. Adonin
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引用次数: 0
Abstract
Novel Ln3+ and 2-iodoterephthalate based metal-organic frameworks [Nd2(2-I-bdc)3(DMF)4]·3.5DMF (1), [Ho2(2-I-bdc)3(DMF)4]·2.7DMF (2), [Yb2(2-I-bdc)3(DMF)4]·4.3DMF (3) (2-I-bdc - 2-iodoterephthalate, DMF - N,N-dimethylformamide) are prepared; their structure is determined by XRD. All three isostructural compounds contain a [Ln2(2-I-bdc)3(DMF)4] binuclear unit (Ln = Nd, Ho, Yb). The 2-I-bdc dianions exhibit two different types of coordination. In the first type, one carboxylate group is connected with one Ln(III) ion by two oxygen atoms and the other one is connected with two metal ions. One oxygen atom of the second carboxylate group is connected with only one metal center of the binuclear fragment, while the second oxygen is a bridging atom.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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