Acyl Migrations Sensitive to Supramolecular Encapsulation

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-25 DOI:10.1039/d5cc01417d

Oleksandra Lagerna, Alexander Shivanyuk, Tetyana Kienko, Svitlana V. Shishkina, Oleg Lukin, Volodymyr Fetyukhin

引用次数: 0

Abstract

Four isomeric resorcin[4]arene tetrabenzoates interconvert via reversible, base-catalysed acyl migrations. Extraction of solid Me4N+I− into a chloroform solution of the isomers gradually shifts the equilibria towards the C2V-symmetric component due to the formation of highly stable hydrogen-bonded molecular capsules.

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对超分子封装敏感的酰基迁移

四种同分异构体间苯二甲酸酯通过可逆的碱催化酰基迁移相互转化。由于形成高度稳定的氢键分子胶囊，将固体Me4N+I -萃取到氯仿溶液中，使平衡逐渐向c2v对称组分转移。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.