A review of cyclodextrins polymers in solid-phase (micro)extraction

IF 21.1 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Today Pub Date : 2025-03-11 DOI:10.1016/j.mattod.2025.02.013

Yingying Wang , Lan He , Weijie Wei , Xiaqing Zhang , Jiang Wang , Jin Li , Zhuwei Gao

{"title":"A review of cyclodextrins polymers in solid-phase (micro)extraction","authors":"Yingying Wang , Lan He , Weijie Wei , Xiaqing Zhang , Jiang Wang , Jin Li , Zhuwei Gao","doi":"10.1016/j.mattod.2025.02.013","DOIUrl":null,"url":null,"abstract":"<div><div>Over the past few decades, CDs (cyclodextrins) and their polymers have been used in pharmaceutical, medical, food, and chromatographic applications due to their special structure of internal hydrophobicity and external hydrophilicity. Therefore, they were extremely useful in solid-phase (micro)extraction. In this review, various synthesis methods of CDs polymers, such as cross-linking polymerization, grafting, self-assembly, molecular imprinting, and cyclodextrin microporous organic networks, were comprehensively introduced. Additionally, the adsorption mechanism of CDs polymers was elaborated. Moreover, the applications of CDs polymers in solid-phase (micro)extraction for food, environmental, and biological samples, along with their excellent properties, were systematically summarized. Finally, the challenges and application prospects of CDs polymers in sample pretreatment were presented. This review was expected to provide valuable references for the development of preparation technologies for CDs polymers with low cost and high adsorption performance.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 212-230"},"PeriodicalIF":21.1000,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Today","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1369702125000628","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Over the past few decades, CDs (cyclodextrins) and their polymers have been used in pharmaceutical, medical, food, and chromatographic applications due to their special structure of internal hydrophobicity and external hydrophilicity. Therefore, they were extremely useful in solid-phase (micro)extraction. In this review, various synthesis methods of CDs polymers, such as cross-linking polymerization, grafting, self-assembly, molecular imprinting, and cyclodextrin microporous organic networks, were comprehensively introduced. Additionally, the adsorption mechanism of CDs polymers was elaborated. Moreover, the applications of CDs polymers in solid-phase (micro)extraction for food, environmental, and biological samples, along with their excellent properties, were systematically summarized. Finally, the challenges and application prospects of CDs polymers in sample pretreatment were presented. This review was expected to provide valuable references for the development of preparation technologies for CDs polymers with low cost and high adsorption performance.

Abstract Image

查看原文本刊更多论文

环糊精聚合物在固相（微）萃取中的研究进展

在过去的几十年里，环糊精及其聚合物由于其内部疏水和外部亲水的特殊结构，在制药、医疗、食品和色谱等领域得到了广泛的应用。因此，它们在固相（微）萃取中非常有用。本文综述了CDs聚合物的各种合成方法，如交联聚合、接枝、自组装、分子印迹、环糊精微孔有机网络等。此外，还阐述了CDs聚合物的吸附机理。此外，系统总结了CDs聚合物在食品、环境和生物样品固相（微）萃取中的应用及其优异的性能。最后指出了CDs聚合物在样品前处理中的挑战和应用前景。本文为开发低成本、高吸附性能的CDs聚合物的制备技术提供了有价值的参考。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Materials Today 工程技术-材料科学：综合

CiteScore

36.30

自引率

1.20%

发文量

237

审稿时长

23 days

期刊介绍： Materials Today is the leading journal in the Materials Today family, focusing on the latest and most impactful work in the materials science community. With a reputation for excellence in news and reviews, the journal has now expanded its coverage to include original research and aims to be at the forefront of the field. We welcome comprehensive articles, short communications, and review articles from established leaders in the rapidly evolving fields of materials science and related disciplines. We strive to provide authors with rigorous peer review, fast publication, and maximum exposure for their work. While we only accept the most significant manuscripts, our speedy evaluation process ensures that there are no unnecessary publication delays.