{"title":"Cover Feature: Single-Atom Based Metal-Organic Frameworks for Efficient C−S Cross-Coupling (Chem. Asian J. 7/2025)","authors":"Gobbilla Sai Kumar, Deepak Kumar, Aditya Thakur, Mukul Gupta, Praveen Kumar Velpula, Rabindranath Lo, Kolleboyina Jayaramulu","doi":"10.1002/asia.202580702","DOIUrl":null,"url":null,"abstract":"<p>Jayaramulu Kolleboyina and co-workers engineered a nickel single-atom catalyst (UiO-66/Ni) with Ni atoms covalently anchored to defect-engineered Zr-oxide clusters in the UiO-66 framework, synthesized via a simple solution impregnation method. This catalyst shows uniform Ni atom distribution, exceptional stability, and high catalytic performance in C–S coupling reactions of aryl thiols and aryl halides, achieving high activity and selectivity across various substituents at room temperature, maintaining stability. More details can be found in article number e202401578.<figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure>\n </p>","PeriodicalId":145,"journal":{"name":"Chemistry - An Asian Journal","volume":"20 7","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/asia.202580702","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - An Asian Journal","FirstCategoryId":"1","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/asia.202580702","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Jayaramulu Kolleboyina and co-workers engineered a nickel single-atom catalyst (UiO-66/Ni) with Ni atoms covalently anchored to defect-engineered Zr-oxide clusters in the UiO-66 framework, synthesized via a simple solution impregnation method. This catalyst shows uniform Ni atom distribution, exceptional stability, and high catalytic performance in C–S coupling reactions of aryl thiols and aryl halides, achieving high activity and selectivity across various substituents at room temperature, maintaining stability. More details can be found in article number e202401578.
期刊介绍:
Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics.
Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews.
A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal.
Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).