Synthesis of heteropnictogen ligands via PI transfer†

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-08 DOI:10.1039/D5CC01162K

Lisa Zimmermann, Michael A. Land, Christoph Riesinger, Charles L. B. Macdonald and Manfred Scheer

引用次数: 0

Abstract

The heterodipnictogen complexes [{CpMo(CO)₂}₂(μ,η^2:2-PE)] (E = P, As, Sb) react with the phosphorus(I) transfer reagent [(BZIMPY)P][CF₃SO₃] (BZIMPY = 2,6-bis(benzimidazole-2-yl)pyridine) in a transmetallation reaction forming the unprecedented [CpMo(CO)₂(η³-P₂E)] complexes.

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通过PI转移合成异烟原配体

杂双烟原配合物[{CpMo(CO)2}2（µ，η:2- pe）] （E = P, As, Sb）与磷(I)转移试剂[(BZIMPY)P][CF3SO3] （BZIMPY = 2,6-二（苯并咪唑-2-酰基）吡啶）发生金属转化反应，形成了前所未有的[CpMo(CO)2(η: 3- p2e)]配合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.