Alexey A. Konnov, Anton D. Lisyutkin, Dmitry B. Vinogradov, Amina A. Nazarova, Alla N. Pivkina, Leonid L. Fershtat
{"title":"Synthesis of 4-Nitroisoxazole-Based Energetic Materials","authors":"Alexey A. Konnov, Anton D. Lisyutkin, Dmitry B. Vinogradov, Amina A. Nazarova, Alla N. Pivkina, Leonid L. Fershtat","doi":"10.1021/acs.orglett.5c01074","DOIUrl":null,"url":null,"abstract":"A set of novel biheterocyclic energetic materials incorporating the 4-nitroisoxazole scaffold was synthesized. Thus, prepared species demonstrated excellent thermal stability (181–244 °C), good densities (1.71–1.74 g·cm<sup>–3</sup>), and detonation velocities (7.6–8.3 km s<sup>–1</sup>), while retaining insensitivity to friction. To the best of our knowledge, this is the first example of an incorporation of the 4-nitroisoxazole scaffold into the structure of high-energy materials.","PeriodicalId":54,"journal":{"name":"Organic Letters","volume":"134 1","pages":""},"PeriodicalIF":4.9000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Letters","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.orglett.5c01074","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
A set of novel biheterocyclic energetic materials incorporating the 4-nitroisoxazole scaffold was synthesized. Thus, prepared species demonstrated excellent thermal stability (181–244 °C), good densities (1.71–1.74 g·cm–3), and detonation velocities (7.6–8.3 km s–1), while retaining insensitivity to friction. To the best of our knowledge, this is the first example of an incorporation of the 4-nitroisoxazole scaffold into the structure of high-energy materials.
期刊介绍:
Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.