Nadia Maté , Elena Bogdan , Lidia Căta , Anamaria Terec , Arie van der Lee , Mihail Bӑrboiu , Niculina D. Hӑdade , Ion Grosu
{"title":"Large multifunctional triphenylamine derivatives as versatile candidates for porous supramolecular materials","authors":"Nadia Maté , Elena Bogdan , Lidia Căta , Anamaria Terec , Arie van der Lee , Mihail Bӑrboiu , Niculina D. Hӑdade , Ion Grosu","doi":"10.1016/j.tet.2025.134630","DOIUrl":null,"url":null,"abstract":"<div><div>The access to novel triphenyl-, tris(biphenyl)- and tris(phenyl-ethynyl-phenyl)amine derivatives decorated with bromine, carboxy or hydroxymethyl groups is developed based on aliphatic nucleophilic substitution and Suzuki-Miyaura and Sonogashira cross-coupling reactions. The target compounds decorated with various groups are able to participate to the formation of self-assembled architectures by hydrogen or halogen bonding.</div></div>","PeriodicalId":437,"journal":{"name":"Tetrahedron","volume":"178 ","pages":"Article 134630"},"PeriodicalIF":2.1000,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0040402025001863","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
The access to novel triphenyl-, tris(biphenyl)- and tris(phenyl-ethynyl-phenyl)amine derivatives decorated with bromine, carboxy or hydroxymethyl groups is developed based on aliphatic nucleophilic substitution and Suzuki-Miyaura and Sonogashira cross-coupling reactions. The target compounds decorated with various groups are able to participate to the formation of self-assembled architectures by hydrogen or halogen bonding.
期刊介绍:
Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry.
Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters.
Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.