{"title":"Synthesis and reactions of malonic esters based on hydroxymethyl-1,3-dioxacycloalkanes","authors":"Yu. G. Borisova, R. M. Sultanova, S. S. Zlotsky","doi":"10.1007/s11172-025-4534-5","DOIUrl":null,"url":null,"abstract":"<div><p>Malonates bearing 1,3-dioxacycloakane moiety were synthesized and some of their reactions were carried out under conditions of conventional heating and microwave irradiation. New malonates can be successfully used as C—H acids in the alkylation reaction as well as for the synthesis of tertiary amines and olefins. The conditions for synthesizing target products in quantitative yields using microwave activation were developed.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"74 2","pages":"428 - 433"},"PeriodicalIF":1.7000,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-025-4534-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Malonates bearing 1,3-dioxacycloakane moiety were synthesized and some of their reactions were carried out under conditions of conventional heating and microwave irradiation. New malonates can be successfully used as C—H acids in the alkylation reaction as well as for the synthesis of tertiary amines and olefins. The conditions for synthesizing target products in quantitative yields using microwave activation were developed.
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.