M. M. Kozlova, V. F. Markov, L. N. Maskaeva, S. Santra, G. V. Zyryanov, A. Majee
{"title":"Oxidative degradation kinetics of ion-exchange resins with the polystyrene-divinylbenzene matrix using the Fenton process","authors":"M. M. Kozlova, V. F. Markov, L. N. Maskaeva, S. Santra, G. V. Zyryanov, A. Majee","doi":"10.1007/s11172-025-4528-3","DOIUrl":null,"url":null,"abstract":"<div><p>The problem of reprocessing of used ion-exchange resins with a polystyrene-divinylbenzene matrix by oxidative degradation using the Fenton process is considered. The kinetics of the process was studied in the presence of 5–25% solutions of H<sub>2</sub>O<sub>2</sub> containing catalytic additives of copper(<span>ii</span>;) and iron(<span>ii</span>;,<span>iii</span>) salts. Electron microscopic studies revealed characteristic changes in the surface morphology and granule shape of the ionexchange resins during oxidative decomposition.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"74 2","pages":"361 - 375"},"PeriodicalIF":1.7000,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-025-4528-3","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The problem of reprocessing of used ion-exchange resins with a polystyrene-divinylbenzene matrix by oxidative degradation using the Fenton process is considered. The kinetics of the process was studied in the presence of 5–25% solutions of H2O2 containing catalytic additives of copper(ii;) and iron(ii;,iii) salts. Electron microscopic studies revealed characteristic changes in the surface morphology and granule shape of the ionexchange resins during oxidative decomposition.
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.