Extraction of f-elements with diglycolamides in polar aliphatic fluorinated diluents

IF 1.5 3区化学 Q3 CHEMISTRY, ANALYTICAL

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2024-12-31 DOI:10.1007/s10967-024-09938-0

Ekaterina Kenf, Lyudmila Tkachenko, Vasiliy Babain, Natalya Sapozhnikova, Mikhail Alyapyshev

引用次数: 0

Abstract

The extraction of f-elements from nitric acid solutions with symmetric diglycolamides in polar aliphatic fluorinated diluents was studied. The influence of diamide structure, namely of the length of alkyl substituents (C4, C6, C8) on amidic nitrogen atom, on the extraction properties was investigated. New extraction solvent on the base of N,N,N′,N′-tetrahexyl diglycolamide in formal of tetrafluorpropyl alcohol (FN-1) was proposed for selective Am (III) separation from PUREX-process raffinates.

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来源期刊

Journal of Radioanalytical and Nuclear Chemistry 化学-分析化学

CiteScore

2.80

自引率

18.80%

发文量

504

审稿时长

2.2 months

期刊介绍： An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.