Synthesis of Nitro Esters of the Lupane Series

IF 0.8 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY

Russian Journal of General Chemistry Pub Date : 2025-03-26 DOI:10.1134/S1070363225600353

I. A. Semenova, T. V. Surkova, Yu. N. Klimochkin

引用次数: 0

Abstract

O-Nitration reactions of betulin and trioxylupane under the action of a nitric acid and acetic anhydride mixture were studied, and effective approaches to the production of mono-, di-, and trinitroesters of the betulin series were developed. A one-stage method for the production of 2,3-seco-28-oxo-19β,28-epoxy-18a-oleane-2,3-dicarboxylic acid from betulin under the action of fuming nitric acid was proposed.

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Lupane系列硝基酯的合成

研究了在硝酸和乙酸酐混合物的作用下，桦木素与三氧丙酮的硝化反应，开发了桦木素系列单、二、三硝基酯的有效生产方法。提出了一种以白桦林为原料，在发烟硝酸作用下一步制得2,3-seco-28-oxo-19β，28-环氧-18a-齐墩烯-2,3-二羧酸的方法。

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来源期刊

Russian Journal of General Chemistry 化学-化学综合

CiteScore

1.40

自引率

22.20%

发文量

252

审稿时长

2-4 weeks

期刊介绍： Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.