Divergent Reduction Chemistry of NHC-Aluminium(III) Hydrides

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-03-26 DOI:10.1039/d5dt00379b

Fáinché Murphy, Alan Kennedy, Catherine Ellen Weetman

引用次数: 0

Abstract

Understanding and controlling facile reduction chemsitry is a key challenge in molecular main group chemistry. Herein, we report the divergent reduction chemistry of aluminium(III) hydrides supported by N-heterocyclic carbenes (NHCs). Choice of reducing agent and NHC ligand are key, with Al(II) dialanes, Al(II) cations, asymmetric Al(II) dialanes and ligand exchange reactions all identitifed via NMR and single crystal X-ray diffraction.

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了解和控制简易还原化学性质是分子主族化学中的一项关键挑战。在此，我们报告了 N-杂环碳化物（NHC）支持的铝（III）氢化物的不同还原化学性质。还原剂和 NHC 配体的选择是关键，铝（II）二烷、铝（II）阳离子、不对称铝（II）二烷和配体交换反应都是通过核磁共振和单晶 X 射线衍射确定的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.