Synthesis and Characterization of New Schiff Base Derivatives from Quinazolinone Moiety and Studying Their Properties as Potential Corrosion Inhibitors

IF 1.1 4区 材料科学 Q3 METALLURGY & METALLURGICAL ENGINEERING
Mohammed G. A. Al-Khuzaie, Shahad F. Ali, Saja Sabbood, Suaad M. H. Al-Majidi, Munaf S. Majeed
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引用次数: 0

Abstract

A new series of Schiff base derivatives of quinazoline core were synthesized through the reaction of quinazoline derivative A with different substituted aromatic aldehydes to produce compounds 1–4. The new Schiff base derivatives 1–4 were obtained in high yields and characterized using various techniques including FTIR, 1H‑NMR, and 13C-NMR. Compounds 1–4 were studied as corrosion inhibitors for carbon steel 45 using polarization curves. Various thermal and kinetic parameters were also examined to better understand the corrosion process and inhibition mechanism of these compounds. All compounds demonstrated excellent corrosion inhibition properties, and the results were corroborated by X-ray diffraction and AFM techniques.

Abstract Image

喹唑啉酮基希夫碱衍生物的合成、表征及潜在缓蚀剂性能研究
通过喹唑啉衍生物A与不同取代芳醛的反应,合成了一系列新的喹唑啉核心希夫碱衍生物,得到化合物1 ~ 4。新的希夫碱衍生物1-4以高收率获得,并使用FTIR, 1H -NMR和13C-NMR等多种技术进行了表征。利用极化曲线研究了化合物1 ~ 4对45碳钢的缓蚀作用。为了更好地了解这些化合物的腐蚀过程和缓蚀机理,还研究了各种热动力学参数。所有化合物都表现出优异的缓蚀性能,并通过x射线衍射和原子力显微镜技术证实了这一结果。
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来源期刊
CiteScore
1.90
自引率
18.20%
发文量
90
审稿时长
4-8 weeks
期刊介绍: Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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